Table 1. 1H and 13C NMR data for 8 and 1H NMR data for 9 (500 MHz for 1H NMR and 125 MHz for 13C NMR).
Position | 1H (8); in CD3OD | 1H (9); in CDCl3 | 13C (8): in CD3OD |
---|---|---|---|
2 | 165.3 | ||
3 | 120.0 | ||
4 | 167.5 | ||
5 | 117.3 | ||
6 | 155.6 | ||
7 | 7.20 d (9.0) | 7.08 d | 115.7 |
8 | 7.24 d (9.0) | 7.15 d | 115.8 |
9 | 148.6 | ||
10 | 123.8 | ||
11 | 2.60 s | 2.61 s | 12.5 |
1′ab | 2.65 m | 23.2 | |
2′ab | 1.65 m | 32.8 | |
3′ | 1.37 m | 36.7 | |
4′a | 3.40 dd, (11, 6) | 67.7 | |
4′b | 3.47 dd, (11, 6) | ||
5′ | 1.01 d (6.7) | 16.9 | |
4-OMe | 3.85 s | 62.3 | |
6-OMe | 3.87 s | 3.85 s | 56.9 |