Table 2. EXAFS fit results for yellow clusters extracted from Villard soil.
Sample | shell | N | R(Å) | σ2(Å2) |
Villard cluster | U-Oax | 2* | 1.787(0.006) | 0.006(0.001) |
U-Oeq | 3.468(0.255) | 2.241(0.005) | 0.006(0.001) | |
U-P | 3.190(1.493) | 3.673(0.117) | 0.030(0.019) | |
MS1 | 8* | 3.725(0.048) | 0.001(0.001) | |
MS2 | 4* | 3.810* | 0.003* | |
U | 5* | 5.061(0.184) | 0.027(0.031) | |
m-autunitea | U-Oax | 2 | 1.774(0.006) | 0.003(0.001) |
U-Oeq | 4 | 2.277(0.006) | 0.004(0.001) | |
U-P | 4 | 3.59(0.002) | 0.005(0.001) | |
MS1 | 8 | 3.71(0.002) | 0.002(0.002) | |
MS2 | 4 | 3.81* | 0.003* | |
U | 4 | 5.210(0.110) | 0.014(0.007) |
N: coordination number, R: radial distance, σ2: Debye-Waller factor. ΔE0 was estimated at 5.733(0.834) for the whole set of shells, and R-factor was 0.027 for the fit of Villard cluster spectrum. The estimated standard deviations are listed in parenthesis.
*: parameter fixed during fitting. MS1: U-Oeq-P multiple scattering path, MS2: U-Oeq-P-Oeq multiple scattering path.
Data published in [32].