. Author manuscript; available in PMC: 2011 Oct 6.

Published in final edited form as: Inorg Chem. 2006 Jul 10;45(14):5465–5478. doi: 10.1021/ic060321x

Table 2.

Selected FeTRENLysCAM bond distances indicating the symmetric orientation of the three chelating arms relative to the tertiary amine (N0) of the Tren cap.

Distances between N0 and Tren-amide nitrogens:
D_N0-N3A (Å)	D_N0-N3B (Å)	D_N0-N3C (Å)
3.024	3.098	3.036
Distances between N0 and Lysine-α-amide nitrogens:
D_N0-N1A (Å)	D_N0-N1B (Å)	D_N0-N1C (Å)
5.527	5.576	5.296
Distances between N0 and Lysine-ε-amide nitrogens:
D_N0-N2A (Å)	D_N0-N2B (Å)	D_N0-N2C (Å)
9.972	9.904	9.480
Distances between N0 and catechol oxygens:
D_N0-O2A (Å)	D_N0-O2B (Å)	D_N0-O2C (Å)
6.551	6.466	6.447
D_N0-O1A	D_N0-O1B	D_N0-O1C
8.715	8.680	8.638