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. Author manuscript; available in PMC: 2012 Oct 19.
Published in final edited form as: J Am Chem Soc. 2011 Sep 21;133(41):16657–16667. doi: 10.1021/ja207131g

Figure 1.

Figure 1

The second order rate constants for oxidation of DHA (squares) and DHA-d4 (circles) by 1 in MeCN −30 ºC under Ar with different concentrations of added H2O. The KIEs obtained at 0, 0.1, 0.5 and 1.0 M added H2O are 9, 9, 10 and 10, respectively.