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. Author manuscript; available in PMC: 2012 Oct 19.
Published in final edited form as: J Am Chem Soc. 2011 Sep 21;133(41):16657–16667. doi: 10.1021/ja207131g

Scheme 4.

Scheme 4

Core structures and spin states of the iron(IV) centers of a series of diiron complexes supported by a common tetradentate ligand, together with their relative rates of DHA oxidation in 3:1 CH2Cl2-MeCN at −80 ºC. Data for the relative reactivities of complexes 2, 4, 5, and 2-OH were taken from ref 37.