Table 1. NMR data for found compound (1 in CD₃CN (600 MHz).

		δH(J in Hz)	δC, mult.	COSYa	HMBCb
Amoa	1		174.8, C
	2	2.70, qd (7.5, 4.1)	44.9, CH	3, 9	1, 3, 4, 9
	3	3.97, m	52.8, CH	2, 4b, 9, NH	1, 2, 4
	4a	1.60, m	29.7, CH2	4b, 5a, 5b	3, 5, 6
	4b	1.11, m		4a, 5a	3, 5, 6
	5a	1.28, m	32.9, CH2	4a, 4b, 5b	4, 7
	5b	1.13, m		4a, 5a	4, 7
	6a	1.28, m	27.1, CH2	6b
	6b	1.12, m		6a
	7	1.27, m	23.8, CH2	8	5, 6
	8	0.86, d (6.2)	14.8, CH3	7
	9	1.13, d (6.9)	15.7, CH3	2	1, 2
	NH	8.93, d (8.9)		3	10
Ala	10		172.7, C
	11	4.35, dq (8.3, 6.9)	52.4, CH	12, NH	10, 12, 13
	12	1.25, d (6.8)	20.8, CH3	11	11, 10
	NH2	6.57, d (8.3)		11	11, 12, 13
N-Me-Phe	13		170.5, C
	14	5.52, dd (10.3, 5.5)	58.4, CH	15a, 15b	13, 15, 16, 22, 23
	15a	3.26, dd (-15.0, 5.5)	34.3, CH2	14, 15b	13, 14, 16, 17, 21
	15b	2.90, dd (-15.0, 10.3)		14, 15a	13, 14, 16, 17, 21
	16		139.6, C
	17	7.18, d (6.9)	130.2, CH	19, 21	15, 18, 19
	18	7.24, m	129.5, CH	17, 19, 21	16, 17
	19	7.18, t (6.9)	127.6, CH	18, 20	17, 18, 20, 21
	20	7.24, m	129.5, CH	17, 19, 21	16, 21
	21	7.18, d (6.9)	130.2, CH	18, 20	15, 19, 20
	22	2.96, s	32.4, CH3		14, 23
Pro	23		175.3, C
	24	4.51,dd (6.9, 3.4)	59.6, CH	25a, 25b	23, 25
	25a	1.80, m	28.8, CH2	24, 25b, 26b	26, 27
	25b	1.57, m		24, 25a, 26a, 26b	23, 24, 26
	26a	2.06, m	27.6, CH2	25b, 26b, 27a, 27b	24, 25
	26b	1.87, m		25a, 25b, 26a, 27a, 27b	25, 27
	27a	3.70, dd (9.0, 9.0)	48.2, CH2	26a, 26b, 27b	24, 25, 28
	27b	3.44, m		26a, 26b, 27a	26
Hmpa	28		170.0, C
	29	5.23, d (2.7)	78.3, CH	30	1, 28, 30, 31, 33
	30	2.15, m	35.4, CH	29, 31a, 31b, 33	31, 32, 33
	31a	1.38, m	24.3, CH2	31b, 32	29, 30, 32, 33
	31b	1.17, m		30, 31a, 32	30, 32, 33
	32	0.87, t (6.9)	12.5, CH3	31a, 31b	30, 31
	33	1.01, d (6.9)	16.4, CH3	30	29, 30, 31

^aCOSY correlations are from proton stated to indicated proton.

^bHMBC correlations are from proton stated to the indicated carbon.