Table 5.
Entry | Reagent | Time | Conversion (%) | ee (%) |
1 | F–TEDAa | <5 h | >90 | 28 |
2 | NFTh | <30 h | >90 | 32.5 |
3 | NFSI | 5 d | 90 | 28.0 |
4 | NFPy | 5 d | 30 | 28.8 |
5 | NFColl | 5 d | <5 | – |
6 | F2-bipy | 7 weeks | 80 | ≤3 |
7 | p-TsN(F)Me | >1 week | 0 | – |
8 | SaSu–NF | >1 week | 0 | – |
a5 mol % of catalyst.