Table 2.
Kinetic Isotope Effects of the HAT Reactions from TBP to [RuIII(dmp−)(TPA)]2+ in MeCN
| kH, M−1 s−1 | kD, M−1 s−1 | kH/kD | |
|---|---|---|---|
| 293 K | (1.6 ± 0.1) × 104 | (7.5 ± 0.6) × 103 | 2.2 |
| 243 K | (7.3 ± 0.4) × 103 | (1.7 ± 0.1) × 103 | 4.3 |
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