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. Author manuscript; available in PMC: 2012 Nov 2.
Published in final edited form as: J Am Chem Soc. 2011 Oct 6;133(43):17180–17191. doi: 10.1021/ja111323m

Scheme 1.

Scheme 1

The factors that affect the energy of the S K-edge pre-edge transition in transition metal-S complexes. L.F =ligand field, −ve = negative, +ve = positive. The colored arrows indicate the direction of the energy shift.