Table II. Reproducibility evaluation based on selected peaks.
Peak No.a | RPLC |
HILIC |
||||||
---|---|---|---|---|---|---|---|---|
tR | m/z | S.D. tRb | RSDc | tR | m/z | S.D. tRb | RSDc | |
1 | 2.1 | 144.10 | 0.19 | 4.8% | 20.3 | 144.10 | 0.21 | 11.4% |
2 | 8.4 | 376.14 | 0.08 | 9.8% | \ | \ | \ | |
3 | 9.0 | 288.28 | 0.13 | 16.7% | 15.1 | 288.28 | 0.35 | 11.4% |
4 | 10.8 | 286.19 | 0.23 | 5.2% | 19.2 | 286.19 | 0.46 | 10.8% |
5 | 12.8 | 314.23 | 0.41 | 10.6% | \ | \ | \ | \ |
6 | 14.9 | 274.26 | 0.38 | 14.2% | \ | \ | \ | \ |
7 | \ | \ | \ | \ | 2.5 | 284.28 | 0.31 | 9.8% |
8 | \ | \ | \ | \ | 10.2 | 312.11 | 0.69 | 19.8% |
9 | \ | \ | \ | \ | 17.9 | 407.77 | 0.33 | 8.4% |
a Peak No. refers to the corresponding peaks in Fig. 1.
b S.D. tR: standard deviation of retention times in six QC samples.
c RSD: relative stand deviation of peak areas in six QC samples.