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. Author manuscript; available in PMC: 2011 Nov 1.
Published in final edited form as: J Chromatogr A. 2007 Aug 30;1168(1-2):3–2. doi: 10.1016/j.chroma.2007.08.054

Table 5.

Effect of temperature and the percent acetonitrile on retention and eluent viscositya. From ref. [109].

ka % ACN (v/v) T (C) ηb (cP) η(T)/ η(25 °C)
1 84.4 25 0.44 1.00
1 76.9 100 0.26 0.60
1 72.1 150 0.19 0.43
1 67.5 200 0.14 0.32
5 69.4 25 0.55 1.00
5 58.6 100 0.29 0.53
5 51.7 150 0.20 0.36
5 44.9 200 0.14 0.25
10 63.0 25 0.60 1.00
10 50.7 100 0.30 0.51
10 42.8 150 0.20 0.33
10 35.2 200 0.14 0.23
a

The table gives the value of ϕACN and T required to obtain the indicated k’ for n-butylbenzene on a Zorbax ODS phase

b

Eluent viscosity calculated at the indicated ϕACN and T.