Table 5.
k’a | % ACN (v/v) | T (C) | ηb (cP) | η(T)/ η(25 °C) |
---|---|---|---|---|
1 | 84.4 | 25 | 0.44 | 1.00 |
1 | 76.9 | 100 | 0.26 | 0.60 |
1 | 72.1 | 150 | 0.19 | 0.43 |
1 | 67.5 | 200 | 0.14 | 0.32 |
5 | 69.4 | 25 | 0.55 | 1.00 |
5 | 58.6 | 100 | 0.29 | 0.53 |
5 | 51.7 | 150 | 0.20 | 0.36 |
5 | 44.9 | 200 | 0.14 | 0.25 |
10 | 63.0 | 25 | 0.60 | 1.00 |
10 | 50.7 | 100 | 0.30 | 0.51 |
10 | 42.8 | 150 | 0.20 | 0.33 |
10 | 35.2 | 200 | 0.14 | 0.23 |
The table gives the value of ϕACN and T required to obtain the indicated k’ for n-butylbenzene on a Zorbax ODS phase
Eluent viscosity calculated at the indicated ϕACN and T.