Figure 5. Nonlinear effects.

(a) Nonlinear behaviour of ee of the monomer pool (ee_mon) as a function of the ee. A strong negative nonlinear effect is observed at low temperatures indicating an asymmetric depletion of the monomer pool. (b) Nonlinear behaviour of ee of monomers present in aggregates (ee_{mon. aggr.}) computed as a function of ee. A strong positive nonlinear effect is observed at high temperatures indicating an enantiomeric enrichment of monomers present in aggregates with respect to the original solution. The thermodynamic parameters and concentration are equivalent to Figure 4a.