Table 1.
Characteristics of poly(NIPAAm-co-HEMAPLA-co-AAc-co-HPG-MA) copolymers with different HPG feed ratios.
| (NIPAAm∣HEMAPLA∣AAc∣HPG-MA) | |||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
GPC
|
LCST (°C)a | ||||||||||||
| Sample ID | Yield | Feed Ratio | 1H NMR (Mn) | Mn |
|
||||||||
| HPG High | 88% | (80∣ | 10∣ | 1∣ | 9) | (79∣ | 1∣ | 3.3∣ | 17) | 3689 | 1.7 | 28 ± 0.1 | |
| HPG Med | 83% | (86∣ | 7∣ | 1∣ | 6) | (85∣ | 8∣ | 0.8∣ | 6) | 3455 | 1.7 | 24 ± 0.2 | |
| HPG Low | 87% | (85∣ | 10∣ | 1∣ | 4) | (85∣ | 11∣ | 0.2∣ | 4) | 4465 | 1.5 | 22 ± 0.1 | |
| Control | 90% | (87∣ | 10∣ | 3∣ | 0) | (86∣ | 12∣ | 1.8∣ | 0) | 1253 | 1.5 | 20 ± 0.4 | |
16.7 wt% in PBS, measured by DSC.