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. Author manuscript; available in PMC: 2011 Nov 11.
Published in final edited form as: Chem Commun (Camb). 2011 Oct 5;47(43):11936–11938. doi: 10.1039/c1cc15124j

Table 1.

Control and reaction conditions for the Ru-Q397C-BM3 and Ru-K97C-BM3 hybrid enzymes and BM3-WT with their respective total turnover numbers (TON)

Entry 10 mM H2O2 100 mM DTC Light TON
1 WT + <2
2 + n.d.
3 + + n.d.
4 WT/Ru(bpy)32+ + n.d.
5 + + <3
6 Ru-K97C-BM3/ + <4
7 Ru-Q397C-BM3 + n.d.
8 + n.d.
9 + + 30/40
60/80a
a

In the presence of 10 μM catalase;

n.d.: not determined because product concentration below detection limit.