Skip to main content
. Author manuscript; available in PMC: 2012 Nov 23.
Published in final edited form as: J Am Chem Soc. 2011 Oct 28;133(46):18816–18827. doi: 10.1021/ja206152m

Figure 3.

Figure 3

The correlation between the Raman and coherence spectra for ferric Ch-CooA. The Raman spectrum (upper red) was measured with excitation at 413.1 nm, whereas the open band (lower green) and detuned (middle blue) coherence spectra were measured at a carrier wavelength of 420 nm. The detuned coherence data were collected with a 0.5 nm spectral window, located 5 nm to the blue of the carrier wavelength (415 nm). The insets show time domain oscillation data (circles) and LPSVD fits (lines) corresponding to the open band (green) and detuned (blue) detection methods. There is a very good correlation between the Raman and coherence spectral frequencies within accuracy of ± 5 cm-1