Table 3.

Tabulation of structural motif assignments for mannan grown on YPD under 37 °C/37 °C conditions based upon the chemical shifts (in ppm) for the anomeric protons of the mannosyl repeat units.

Label	Chemical Shifts (ppm) H-1	Structural Feature
a	5.568	β-Man-(1→2)-α-Man-(1→PO4
b	5.556	β-Man-(1→ [β-Man-(1→2)]n2)-β-Man-(1→2)-α-Man-(1→PO4
c	5.474	α-Man-(1→PO4
d	5.385	α-Man-(1→2)-α-Man-(1→3)-α-Man-(1→
a′	5.375	α-Man-(1→2)-α-Man-(1→3)-α-Man-(1→2)
b′	5.373	α-Man-(1→2)-α-Man-(1→3)-α-Man-(1→2)
e	5.308	α-Man-(1→3)-[? →]-α-Man-(1→2)-α-Man-(1→3)[α-Man-(1→6)]-α-Man-(1→2)-
f	5.291	α-Man-(1→3)-α-Man-(1→6)-α-Man-(1→2)-α-Man-(1→3)][α-Man-(1→6)]-α-Man-(1→2)
g	5.282	α-Man-(1→2)-α-Man-(1→2)
h	5.276	α-Man-(1→2)-α-Man-(1→2)
h	5.260	α-Man-(1→2)-α-Man-(1→2)
c′	5.257	α-Man-(1→2)-α-Man-(1→2)-α-Man-(1→2)
d′	5.247	α-Man-(1→2)-α-Man-(1→2)
e′	5.226	α-Man-(1→3)-α-Man-(1→6)-α-Man-(1→2)-α-Man-(1→2)
i	5.183	β-Man-(1→2)-α-Man-(1→2)
i	5.179	β-Man-(1→2)-α-Man-(1→
j	5.163	β-Man-(1→2)-α-Man-(1→2)
f′	5.157	α-Man-(1→3) ?
g′	5.131	α-Man-(1→3)
k	5.121	→6)-α-Man-(1→ a
l	5.110	→6)-α-Man-(1→ a
m	5.095	→6)-α-Man-(1→ a
h′	5.072	α-Man-(1→6)-[α-Man-(1→2)]-α-Man-(1→6)-α-Man-(1→6)
n	5.064	α-Man-(1→2; →6)-α-Man-[α-Man-(1→2)-α-Man]-(1→
i′	5.053	α-Man-(1→6(→2)α-Man-(1→6(α-Man-(1→2)-α-Man-(1→6(→2)-α-Man-(1→6
p	4.939	β-Man-(1→2)-[β-Man-(1→2)]n-α-Man-(1→b
q	4.928	α-Man-(1→6)
r	4.915	β-Man-(1→ [β-Man-(1→2]n2)-β-Man-(1→2)-α-Man-(1→PO4
s	4.902	β-Man-(1→ [β-Man-(1→2]n2)-β-Man-(1→2)-α-Man-(1→PO4
j′	4.890	β-Man-(1→ [β-Man-(1→2]n2)-β-Man-(1→2)-α-Man-(1→PO4
t	4.855	β-Man-(1→2)-β-Man-(1→2)-α-Man-(1→2(3)
t	4.853	β-Man-(1→2)-β-Man-(1→2)-α-Man-(1→PO4
u	4.832	β-Man-(1→2)-α-Man-(1→PO4
v	4.784	β-Man-(1→2)-α-Man-(1→

^aRepeat unit along the backbone with different side chains attached.

^bChemical shift for the anomeric proton of Man next to terminal β–Man-(1→