Table 2. The effective magnetic moment (μeff) [9] of the four lanthanide ion complexes and the measured T1 (sec) ± s.d. of bulk water in 20 mM samples of LnDOTA-(gly)4 −.
Ln | μeff | Bulk water T1 (sec) of Ln-1 | CEST (%)1-(Mon/Moff) |
Yb | 4.5 | 1.86±0.01 | 49 |
Tm | 7.6 | 0.53±0.01 | 25 |
Dy | 10.6 | 0.24±0.01 | 15 |
Tb | 9.7 | 0.25±0.01 | 17 |
All data were collected at 9.4 T, 310 K on samples adjusted to pH 7.5.