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Carbon-13 nuclear magnetic resonance (13C NMR) spectrum of poly(ɛ-caprolactone) (PCL), poly(propylene adipate) (PPAd), and their copolymer PPAd/PCL 65/35 weight/weight (A) and 13C-NMR spectrum at region 173 ppm of PPAd/PCL 65/35 weight/weight (B).