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. 2011 Nov 22;6:2981–2995. doi: 10.2147/IJN.S26568

Table 1.

Theoretical and calculated compositions, intrinsic viscosities, and molecular weights of prepared polymers

Sample %wt %mol %mol 1H NMR %mol 13C NMR* [η] (dL/g) Average Mn (g/mol) Average Mw (g/mol) Mw/Mn
PCL 0/100 0/100 0/100 0/100 0.53 15,300 47,700 3.12
PPAd/PCL 10/90 10/90 6.37/93.63 6.12/93.88 6.74/93.26 0.42 19,300 50,500 2.61
PPAd/PCL 20/80 20/80 13.28/86.72 12.97/87.03 13.36/86.64 0.53 12,300 32,800 2.67
PPAd/PCL 30/70 30/70 20.80/79.20 23.31/76.69 21.27/78.73 0.40 13,200 34,300 2.60
PPAd/PCL 55/45 55/45 42.82/57.18 43.13/56.87 44.15/55.85 0.41 16,900 36,100 2.13
PPAd/PCL 65/35 65/35 53.24/46.76 55.45/44.55 55.33/44.67 0.42 19,400 38,600 1.99
PPAd/PCL 85/15 85/15 77.62/22.38 77.07/22.93 79.98/20.02 0.43 11,000 24,900 2.26
PPAd 100/0 100/0 100/0 100/0 0.57 13,700 28,900 2.10
*

Note: Estimated from diol carbons a from polycaprolactone, bonded to the ester oxygen.

Abbreviations: 1H NMR, hydrogen-1 nuclear magnetic resonance; 13C NMR, carbon-13 nuclear magnetic resonance; %mol, percentage concentration; %wt, weight percent; Mn, number average molecular weight; Mw, weight average molecular weight; PCL, poly(ɛ-caprolactone); PPAd, poly(propylene adipate).