Table 1.
Sample | %wt | %mol | %mol 1H NMR | %mol 13C NMR* | [η] (dL/g) | Average Mn (g/mol) | Average Mw (g/mol) | Mw/Mn |
---|---|---|---|---|---|---|---|---|
PCL | 0/100 | 0/100 | 0/100 | 0/100 | 0.53 | 15,300 | 47,700 | 3.12 |
PPAd/PCL 10/90 | 10/90 | 6.37/93.63 | 6.12/93.88 | 6.74/93.26 | 0.42 | 19,300 | 50,500 | 2.61 |
PPAd/PCL 20/80 | 20/80 | 13.28/86.72 | 12.97/87.03 | 13.36/86.64 | 0.53 | 12,300 | 32,800 | 2.67 |
PPAd/PCL 30/70 | 30/70 | 20.80/79.20 | 23.31/76.69 | 21.27/78.73 | 0.40 | 13,200 | 34,300 | 2.60 |
PPAd/PCL 55/45 | 55/45 | 42.82/57.18 | 43.13/56.87 | 44.15/55.85 | 0.41 | 16,900 | 36,100 | 2.13 |
PPAd/PCL 65/35 | 65/35 | 53.24/46.76 | 55.45/44.55 | 55.33/44.67 | 0.42 | 19,400 | 38,600 | 1.99 |
PPAd/PCL 85/15 | 85/15 | 77.62/22.38 | 77.07/22.93 | 79.98/20.02 | 0.43 | 11,000 | 24,900 | 2.26 |
PPAd | 100/0 | 100/0 | 100/0 | 100/0 | 0.57 | 13,700 | 28,900 | 2.10 |
Note: Estimated from diol carbons a from polycaprolactone, bonded to the ester oxygen.
Abbreviations: 1H NMR, hydrogen-1 nuclear magnetic resonance; 13C NMR, carbon-13 nuclear magnetic resonance; %mol, percentage concentration; %wt, weight percent; Mn, number average molecular weight; Mw, weight average molecular weight; PCL, poly(ɛ-caprolactone); PPAd, poly(propylene adipate).