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. 2010 Aug 26;10(9):7947–7978. doi: 10.3390/s100907947

Table 11.

Micro-sensors for organophosphate and carbamates (in italics) determination in water. WFD priority organic substance in bold type.

Method Compound LoD Ref.
Colorimetry on gold nanoparticles Chlorpyrifos
Malathion
20 μg/L
100 μg/L
[146]
Guided shear horizontal surface acoustic wave devices on LiTaO3 Phosmet
Parathion
5 mg/L
2 mg/L
[149]
Voltammetry on clay modified electrodes containing Ni2Al-NO3 Glyphosate
Glufosinate
169 μg/L
905 μg/L
[150]
Amperometric activity measurement of acetylcholinesterase immobilized on screen-printed graphite electrode Chlorpyrifos 2 μg/L [151,152]
Voltammetry on glassy carbon electrode modified with a poly-L-cysteine film Methyl parathion 1.7 μg/L [153]
Amperometric activity measurement of acetylcholinasterase immobilized on gold nanoparticles and silk fibroin modified platinum electrode Methyl paraoxon
Carbofura
Phoxim
6 ng/L
7 ng/L
0.6 μg/L
[148]
Amperometric activity measurement of acetylcholinesterase immobilized on calcium carbonate-chitosan composite film Methyl parathion 1 μg/L [154]
Amperometric activity measurement of acetylcholinesterase and choline oxidase within separate hybrid mesoporous silica membranes Diazinon-oxon 0.37 μg/L [155]
Amperometric activity measurement of acetylcholinesterase on gold-platinum bimetallic nanoparticles onto 3-amino-propyltriethoxy silane modified glassy carbon electrode Paraoxon ethyl
Sarin
Aldicarb
9.5 μg/L
6 μg/L
48 μg/L
[156]
Amperometric activity measurement of acetylcholinesterase on poly(dimethosiloxane)-poly(diallydimethylammonium)/gold nanoparticles composite film Paraoxon
Parathion
0.5 ng/L
1.0 ng/L
[147]
Voltammetry on nano-alumine film modified electrode Parathion 0.3 μg/L [157]
Amperometric reactivation measurement of cholinesterase from organophosphorus-inhibited rat saliva on carbon nanotube modified screen printed carbon electrode Paraoxon 0.14 μg/L [158]
*

LoD: Limit of Detection.