Table 1.

Enantioselective Allylation of Cyclic Enones.

Enonea	Yieldb	Product	ee
1 1a	84%	3a	98% ee
2 1bc,d	46%	3b	97% ee
3 1c	92%	3c	93% ee
4 1d	95%	3d	92% ee
5 1e	89%	3e	85% ee

^aAdditions were carried out using 5 mol % (S)-3,3′-dibromobinol.

^bYields are for pure isolated substances.

^cAddition was effected using 5 mol % (R)-3,3′-dibromobinol.

^dBoth the starting material and the product were volatile.