Table 3.

Effect of split mode, analysis time and second dimension cycle time on corrected 2D peak capacity and corrected 2D peak capacity production rate.

a) 12 s		Analysis Time [min]
		15		30		60
	Split Mode	split-less	split	split-less	split	split-less	split
	1nc, measured a	37	149	88	181	157	232
	2nc, measured b	24	24	24	24	24	24
	<β> c	2.5	4.5	2.0	2.8	1.7	1.9
	n′c, 2D d	360	793	1073	1534	2257	2912
	n′c, 2D / tan [peaks/min] e	24	53	36	51	38	49
b) 21 s		Analysis Time [min]
		15		30		60
	Split Mode	split-less	split	split-less	split	split-less	split
	1nc, measured a	37	149	88	181	157	232
	2nc, measured b	32	32	32	32	32	32
	<β> c	4.1	7.8	3.1	4.7	2.5	3.0
	n′c, 2D d	291	614	899	1221	1975	2456
	n′c, 2D / tan [peaks/min] e	19	41	30	41	33	41

^aFirst dimension peak capacity calculated by eq. (7) using measured average peak width;

^bSecond dimension peak capacity calculated by eq. (8) using measured average peak;

^cFirst dimension peak broadening factor calculated by eq. (4);

^dCorrected 2D peak capacity calculated by eq. (5);

^eCorrected 2D peak capacity production rate relative to analysis time.