Table 4.
a) 12 s | Analysis Time [min] | ||||||
---|---|---|---|---|---|---|---|
15 | 30 | 60 | |||||
Split Mode | split-less | split | split-less | split | split-less | split | |
n′c, 2D a | 360 | 793 | 1073 | 1534 | 2257 | 2912 | |
n′c, 2D Ratio b | 2.20 | 1.43 | 1.29 | ||||
# Observed Peaks | 36 | 113 | 111 | 158 | 165 | 213 | |
# Peaks Ratio c | 3.14 | 1.42 | 1.29 | ||||
b) 21 s | Analysis Time [min] | ||||||
15 | 30 | 60 | |||||
|
|||||||
Split Mode | split-less | split | split-less | split | split-less | split | |
n′c, 2D a | 291 | 614 | 899 | 1221 | 1975 | 2456 | |
n′c, 2D Ratio b | 2.11 | 1.36 | 1.24 | ||||
# Observed Peaks | 43 | 80 | 103 | 128 | 154 | 184 | |
# Peaks Ratio c | 1.86 | 1.24 | 1.19 |
Corrected 2D peak capacity calculated by eq. (5);
Ratio of measured corrected 2D peak capacity for split to split-less mode;
Ratio of the number of observed peaks for split to split-less mode.