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. Author manuscript; available in PMC: 2012 Dec 15.
Published in final edited form as: J Phys Chem B. 2011 Nov 21;115(49):14846–14851. doi: 10.1021/jp207841m

Scheme 1.

Scheme 1

The structure of N-acetylproline (N-AcPro) showing the preferred cleavage site at N-Cα(N1-C2) after electron addition which occurs at both the carboxyl and acetyl groups. The second dashed line shows an alternative cleavage site not found in this work.