Table 1.
Letter and Structure | Chemical Group | Chemical Shift, ppm | T1, ms | T2a, ms |
---|---|---|---|---|
A (methyl protons) | -CH3 | 0.90 | 1,071 ± 27 | 41 ± 18 |
B (methylene protons) | -(CH2)n- | 1.30 | 549 ± 16 | 52 ± 17 |
C (methylene protons β to COO) | -CH2-CH2-COO | 1.59 | 470 ± 15 | 40 ± 8 |
D (methylene protons α to C=C) | -CH2-CH=CH-CH2- | 2.04 | 502 ± 11 | 32 ± 4 |
E (methylene protons α to COO) | -CH2-COO | 2.25 | 465 ± 22 | 36 ± 3 |
F (diallylic methylene protons) | =CH-CH2-CH= | 2.77 | 629 ± 72 | 40 ± 3 |
G (methylene glycerol backbone) | CH2-O | 4.10 | ||
H (methylene glycerol backbone) | CH2-O | 4.25 | ||
I (methine glycerol backbone) | CH-O | 5.22 | 44 | |
J (methine protons) | -CH=CH- | 5.31 | 42 ± 19 |
Resonance assignments by letter correspond to Figure 1. Values are mean ± 1 SD.
Apparent T2; Although the decay curves were fitted with single exponential, there may be additional J-coupling contributions to the decay.