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. Author manuscript; available in PMC: 2012 Jan 1.
Published in final edited form as: Chem Sci. 2011;2:2196–2198. doi: 10.1039/c1sc00414j

Table 3.

Catalytic asymmetric γ additions of aryl thiols to allenoates: Variation of the aryl thiola

graphic file with name nihms343995u4.jpg
entry R ee (%) yield (%)b
1 H 90 73
2 2-OMe 90 67
3 3,5-dimethyl 92 81
4 4-F 91 64
5 4-Cl 91 59
6 4-OMe 91 76
7 4-NH2 86 64
a

All data are the average of two experiments.

b

Yield of purified product.