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. 2011 Dec 14;51(1):425–438. doi: 10.1021/ic2018693

Figure 1.

Figure 1

(a) HDO in bulk water, νO–D = 2509 cm–1, dO(···D)–O = 2.89 Å. (b) HDO affected by a structure making cation, νO–D < 2509 cm–1, dO(···D)–O < 2.89 Å. (c) HDO affected by a structure breaking cation, νO–D > 2509 cm–1, dO(···D)–O > 2.89 Å. O–D bond strength is indicated by the line thickness, and orange color represent a D atom.