Table 3. Mean Bond Distances, d/Å, Number of Distances, N, Temperature Coefficients, b/Å2, and the Half-Height Full Width, l/Å, in the LAXS Studies of the Dimethyl Sulfoxide Solvated Alkali Metal Ions in Solution at Room Temperature.
species | interaction | N | d | b | l |
---|---|---|---|---|---|
Sodium Iodide in Me2SO, 1.017 mol·dm–3 | |||||
Na(OSMe2)6+ | Na–O | 6 | 2.43(2) | 0.020(2) | 0.20(1) |
Na···S | 6 | 3.70(2) | 0.040(2) | 0.28(1) | |
Potassium Iodide in Me2SO, 1.017 mol·dm–3 | |||||
K(OSMe2)7+ | K–O | 7 | 2.790(7) | 0.0200(13) | 0.200(6) |
K···S | 7 | 4.060(8) | 0.042(2) | 0.29(1) | |
Cesium Iodide in Me2SO, 1.000 mol·dm–3 | |||||
Cs(OSMe2)8+ | Cs–O | 8 | 3.061(8) | 0.0234(8) | 0.216(4) |
Cs···S | 8 | 4.279(7) | 0.056(2) | 0.33(1) |