Skip to main content
. 2011 Dec 14;51(1):425–438. doi: 10.1021/ic2018693

Table 3. Mean Bond Distances, d/Å, Number of Distances, N, Temperature Coefficients, b2, and the Half-Height Full Width, l/Å, in the LAXS Studies of the Dimethyl Sulfoxide Solvated Alkali Metal Ions in Solution at Room Temperature.

species interaction N d b l
Sodium Iodide in Me2SO, 1.017 mol·dm–3
Na(OSMe2)6+ Na–O 6 2.43(2) 0.020(2) 0.20(1)
Na···S 6 3.70(2) 0.040(2) 0.28(1)
Potassium Iodide in Me2SO, 1.017 mol·dm–3
K(OSMe2)7+ K–O 7 2.790(7) 0.0200(13) 0.200(6)
K···S 7 4.060(8) 0.042(2) 0.29(1)
Cesium Iodide in Me2SO, 1.000 mol·dm–3
Cs(OSMe2)8+ Cs–O 8 3.061(8) 0.0234(8) 0.216(4)
Cs···S 8 4.279(7) 0.056(2) 0.33(1)