Table 4. Affected Spectra Peaks Are Linear Combinations of Gaussian Peaksa.
| center (cm–1) | weighted (cm–1) | assignment | |
|---|---|---|---|
| CsI (N = 7.4) | 2567 | 2567 | affected spect. |
| 2568 | I– | ||
| 2402 | noise | ||
| RbI (N = 8.9) | 2565 | 2560 | affected spect. |
| 2566 | I– | ||
| 2491 | noise | ||
| KI (N = 10.6) | 2559 | 2549 | affected spect. |
| 2564 | I– | ||
| 2508 | K+/noise | ||
| NaI (N = 9.6) | 2566 | 2563 | affected spect. |
| 2568 | I– | ||
| 2542 | 2539 | Na+ | |
| 2542 | Na+, main | ||
| 2374 | Na+, assym | ||
| NaClO4(N = 11.6) | 2544 | 2559 | affected spect. |
| 2633 | ClO4– | ||
| 2544 | 2540 | Na+ | |
| 2544 | Na+, main | ||
| 2398 | Na+, assym | ||
| LiClO4(N = 10.3) | 2626 | 2536 | affected spect. |
| 2630 | ClO4– | ||
| 2558 | Li+ | ||
| 2564 | Li+, second shell | ||
| 2490 | Li+, first shell | ||
| 2449 | not explained |
a
For NaI, NaClO4 and LiClO4, the cationic contribution is also a linear combination of Gaussian peaks (given in italics).