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. Author manuscript; available in PMC: 2013 Jan 6.
Published in final edited form as: J Org Chem. 2011 Nov 28;77(1):300–310. doi: 10.1021/jo201948e

Table 4.

DABCO mediated stereospecific cross coupling of ethyl-Z-3-iodoacrylate with phenols and N-heterocycles

graphic file with name nihms341202t30.jpg
Entry Product Yield (%) Entry Product Yield (%)
1 graphic file with name nihms341202t31.jpg 98 6 graphic file with name nihms341202t32.jpg 92
2 graphic file with name nihms341202t33.jpg 93b 7 graphic file with name nihms341202t34.jpg 96b
3 graphic file with name nihms341202t35.jpg 84 8 graphic file with name nihms341202t36.jpg 93
4 graphic file with name nihms341202t37.jpg 95b 9 graphic file with name nihms341202t38.jpg 84b
5 graphic file with name nihms341202t39.jpg 96 10 graphic file with name nihms341202t40.jpg 84b
a

Isolated yields, the average of at least two runs.

b

The reaction was carried out at rt and was stirred for 3 h.