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. Author manuscript; available in PMC: 2012 Dec 23.
Published in final edited form as: Tetrahedron. 2011 Dec 23;67(51):9809–9828. doi: 10.1016/j.tet.2011.09.035

Table 4.

Model Stille coupling to afford (+)-136

graphic file with name nihms327891u5.jpg
Entry Additive Geometric Isomers
1 --- mixture
2 Ph2PO2NBu4 (1.5 equiv) mixture
3 Ph2PO2NBu4 (6 equiv) pure Z,Z,E isomer