TABLE 1.

Rate constants obtained for the formation of the external aldimine in PLP-OAM determined by global analysis of the singular value decomposition-transformed PDA data shown in Fig. 7

Experimental conditions are described under “Experimental Procedures.”

	d-Ornithine	dl-2,4-Diaminobutryic acid
k1 (s-1) A > B	7.86 ± 0.03	3.93 ± 0.09
k-1 (s-1) B > A	0.03 ± 0.01	0.02 ± 0.01
k2 (s-1) B > C	0.45 ± 0.01	0.77 ± 0.01
k-2 (s-1) C > B	3.1 × 10-3 ± 2 × 10-4	9.6 × 10-5 ± 6 × 10-6
k3 (s-1) C > D	4.7 × 10-2 ± 2 × 10-4	6.2 × 10-2 ± 1 × 10-4
k-3 (s-1) D > C	1.7 × 10-4 ± 1.7 × 10-4	1.7 × 10-6 ± 3 × 10-7