Table 3.
Laser-based spectroscopic applications to environmental gases and aerosols.
Element | Sample | Sample Preparation | Method | LOD | Notes | Reference |
---|---|---|---|---|---|---|
Hg | Air | Direct analysis | LEAFS | 0.1 ng/m3 | Double resonance excitation, quartz cell | [134] |
Al, Ca, Cr, Cu, Mg, Mn, Na | Urban aerosol | PM2.5 cyclonic inlet and virtual impactor | LIBS | 15-185 fg | Field experiment at Pittsburgh Aerosol Supersite | [135] |
Al, Ba, Ca, Cl, Fe, Mg, Na, P | Urban bioaerosol | Direct analysis | LIBS | Not given | Comparison to aerosol mass spectrometry, 0.1–2 μm aerosols can be quantified | [133] |
Many (14) | Aerosol | Cascade impactor, greased aluminum substrate | LIBS | Not given | Particles from steel making, composition shows size dependence | [136] |
Al, C, Ca, Fe, N, Na, O, P, S, Si | Inorganic aerosol | Impactor or passive deposition | micro-Raman | Not given | >1 μm diameter, organic and mixed particles more problematic | [137] |