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. Author manuscript; available in PMC: 2012 Apr 25.
Published in final edited form as: J Org Chem. 2010 Oct 25;75(22):7682–7690. doi: 10.1021/jo101498b

Table 5.

Thermal Phase Behavior Characterization - 1:1 Mixtures of D1-10:N3

Derivative graphic file with name nihms248107t1.jpg
D1N3 Iso 132 [−7] graphic file with name nihms248107t2.jpg 86 [−22] Cr
D2N3 Iso 134 [−7] graphic file with name nihms248107t2.jpg 85 [−25] graphic file with name nihms248107t2.jpg 73 [−15] Cr
D3N3 Iso 129 [−11] graphic file with name nihms248107t2.jpg 66 [−46] Cr
D4N3 Iso 131 [−10] graphic file with name nihms248107t2.jpg 77 [−67] Cr
D5N3 Iso 123 [−21] graphic file with name nihms248107t2.jpg 60 [−49] Cr
D6N3 Iso 123 [−21] graphic file with name nihms248107t2.jpg 75 [−72] Cr
D7N3 Iso 129 [−14] graphic file with name nihms248107t2.jpg 66 [−71 ] Cr
D8N3 Iso 133 [−17] graphic file with name nihms248107t2.jpg 78 [−85] Cr
D9N3 Iso 125 [−7]b graphic file with name nihms248107t2.jpg 123a [−38] Cr
D10N3 Iso 131 [−17] graphic file with name nihms248107t2.jpg 120 [−0.4] Cr

Temperatures (°C) and enthalpies (KJ/mol) in brackets for phase transitions determined by DSC upon cooling 2°C/min. Tc is a transition upon cooling. Iso = isotropic and Cr = final crystalline state.

(a)

Transition is composed of multiple peaks.