Table 2.
Efficiency of MRM specific transitions for LA-NO2 and OA-NO2. The efficiency is expressed relative to the maximum signal obtained, which corresponds to the fragmentation following the formation of the NO2− product ion (324.2→46 and 326.2→46 for LA-NO2 and OA-NO2, respectively)
| MRM transition | Product ion efficiency (%) |
|---|---|
| 9-NO2-LA | |
| 324.2 → 46 | 100 |
| 324.2 → 168.1 | 7.9 |
| 324.2 → 210.1 | 1.5 |
| 324.2 → 224.1 | 3.3 |
| 10-NO2-LA | |
| 324.2 → 46 | 100 |
| 324.2 → 182.1 | 1.3 |
| 324.2 → 224.1 | 3.3 |
| 324.2 → 238.1 | 0.2 |
| 12-NO2-LA | |
| 324.2 → 46 | 100 |
| 324.2 → 157.1 | 7.3 |
| 324.2 → 171.1 | 14.2 |
| 324.2 → 195.1 | 1.4 |
| 324.2 → 213.1 | 0.8 |
| 13-NO2-LA | |
| 324.2 → 46 | 100 |
| 324.2 → 171.1 | 14.1 |
| 324.2 → 185.1 | 8.2 |
| 324.2 → 209.1 | 4.8 |
| 324.2 → 227.1 | 2.8 |
| 9-NO2-OA | |
| 326.2 → 46 | 100 |
| 326.2 → 168.1 | 4.6 |
| 10-NO2-OA | |
| 324.2 → 46 | 100 |
| 326.2 → 169.1 | 2.0 |