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. Author manuscript; available in PMC: 2012 Feb 28.
Published in final edited form as: Inorg Chem. 2012 Jan 20;51(4):2393–2402. doi: 10.1021/ic202379b

Chart 1.

Chart 1

The [Fe2(μ-O)2(5-Et-TPA)2]3+ complex (left) was the first di(μ-oxo)diiron(III,IV) species structurally characterized by X-ray crystallography. The [Fe2(μ-O)(OH)(H2O)(R3TPA)2]3+ (1, right) compound was reported to be a versatile starting material for generating diiron(IV) species.