Official websites use .gov
A
.gov website belongs to an official
government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you've safely
connected to the .gov website. Share sensitive
information only on official, secure websites.
Diazo Decomposition of 19
 | ||||||
|---|---|---|---|---|---|---|
| Entry | Catalyst | Solvent | Temp (°C) | Time (h) | Product | %Yield |
| 1 | Rh2(OAc)4 (10 mol %) | benzene | rt | 4 | 20 | 67% |
| 2 | Rh2(OAc)4 (10 mol %) | benzene | 40 | 1.5 | 20 | 67% |
| 3 | Rh2(OAc)4 (10 mol %) | benzene | 75 | 2 | 20 | 75% |
| 4 | CuOTf (80 mol %) | CH2Cl2 | rt | 1 | 18 | 51% |
| 5 | CuOTf (40 mol %) | CH2Cl2 | reflux | 1 | 18 | 47% |
| 6 | CuOTf (60–80 mol %) | benzene | rt | 2 | 18 | 51% |
| 7 | HBF4 (4 - 8 eq.) | CH2Cl2 | rt | > 24 | decomposition | - |
| 8 | HBF4 (4 - 8 eq.) | CH2Cl2 | reflux | 4 | decomposition | - |
| 9 | h (λ ≥ 254 nm) | CCl4 | rt | 12 | 19 + baseline | - |
