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. Author manuscript; available in PMC: 2013 Jun 19.
Published in final edited form as: Acc Chem Res. 2011 Oct 21;45(6):826–839. doi: 10.1021/ar200194b

Scheme 10.

Scheme 10

A) Synthesis of bursehernin (42) via innate C–H enolate coupling;14,15 B) Structures of avrainvillamide (44), stephacidin A (43) and B (45); C) Innate C–H enolate coupling in the synthesis of 44, 43 and 45.17