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. Author manuscript; available in PMC: 2013 Jun 19.
Published in final edited form as: Acc Chem Res. 2011 Oct 21;45(6):826–839. doi: 10.1021/ar200194b

Scheme 14.

Scheme 14

A) Cyclase phase synthesis resulting in the formation of sesquiterpene dihydrojunenol (64);21,22 B) Synthesis of eudesmane natural products (65–68) from dihydrojunenol (64) by innate and guided C–H oxidation.21