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. Author manuscript; available in PMC: 2013 Mar 14.
Published in final edited form as: Chem Rev. 2011 Oct 21;112(3):1681–1709. doi: 10.1021/cr200073d

Scheme 27.

Scheme 27

Oxygen activation catalyzed by Fe(II)/α-KG-dependent enzymes and the proposed mechanism of H6H catalyzed two-electron oxidation of a secondary alcohol to generate scopolamine (162).