Table 5.

Relative Band Areas

Chemical Shifts (ppm)	Normal		MGD		Tentative Assignment†
	A/A1.39ppm	A/A4.1ppm	A/A1.39ppm	A/A4.1ppm
0.09	0.0067 ± 0.0046	0.045 ± 0.012	0.00063 ± 0.00008	0.032 ± 0.004	No Assignment
0.72	0.0015 ± 0.0002	0.012 ± 0.03	0.0017 ± 0.0003	0.15 ± 0.03	No Assignment
0.89	0.022 ± 0.003	1.7 ± 0.4	0.025 ± 0.003	1.7 ± 0.2	─CH3, except n-3
0.94	0.004 ± 0.001	0.21 ± 0.03	0.0033 ± 0.0003	0.19 ± 0.02	─CH3, n-3
1.03	0.0014 ± 0.0002	0.9 ± 0.02	0.0017 ± 0.0003	0.11 ± 0.02	─CH2OHCH2 CH3 ─CH2─CH─(CH3)2, isobranched
1.26	0.0041 ± 0.0002	0.29 ± 0.06*	0.0037 ± 0.0001	0.18 ± 0.02*	─COO(CH2)nCH3, short-chain esters
1.29	0.058 ± 0.009	0.48 ± 0.09	0.054 ± 0.007	0.4 ± 0.1	─COO(CH2)nCH3, short-chain esters
1.39	1	38 ± 4	1	40 ± 5	─(CH2)n─, core
1.70	0.43 ± 0.04	36 ± 7	0.52 ± 0.005	45 ± 7	R─CH2─CH2─COO─R
4.10	0.026 ± 0.003	1	0.025 ± 0.003	1	ROCH2─alkyl, wax ester
4.18	0.003 ± 0.001	0.20 ± 0.04	0.003 ± 0.001	0.13 ± 0.01	CHCH2OR; C1, 3 protons, glyceryl. 4 H per molecule
4.25	0.0036 ± 0.0004	0.25 ± 0.05	0.0033 ± 0.0003	0.27 ± 0.04	C1, 3 protons, glyceryl
4.60	0.0047 ± 0.0008	0.28 ± 0.04*	0.0036 ± 0.0007	0.17 ± 0.02*	R─O─CH, C3 of cholesterol ester
5.00	0.042 ± 0.008	3.3 ± 0.8*	0.033 ± 0.005	1.6 ± 0.2*	─CH═CH─, conjugated
5.20	0.036 ± 0.003	2.7 ± 1.1	0.016 ± 0.005	1.7 ± .7	─CH═CH─, conjugated
5.45	0.21 ± 0.01	13 ± 2	0.20 ± 0.02	17 ± 2	─CH═CH─
7.90	0.009 ± 0.001	0.77 ± 0.13	0.0065 ± 0.0005	0.53 ± 0.08	Hydroperoxides
9.65	0.0026 ± 0.0008	0.014 ± 0.002	0.0017 ± 0.006	0.0098 ± 0.0024	trans-2-Alkenals
9.71	0.00026 ± 0.00004	0.0037 ± 0.0009	0.00045 ± 0.00009	0.0064 ± 0.0015	R─CH═O, n-alkenals

^*Significantly different, P < 0.05.

^†The bold underlined proton is the proton for which the tentative assignment was made.