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. Author manuscript; available in PMC: 2013 Mar 2.
Published in final edited form as: J Org Chem. 2012 Feb 8;77(5):2486–2495. doi: 10.1021/jo300181f

Figure 10.

Figure 10

Rate dependence on delay time between addition of water and 3d. Plot of the rates of hydrolysis of (R)-1,2-epoxyhexane ([epoxide]i = 5.4 M) in 1,2-hexanediol versus conversion of water ([H2O]i = 3.1 M) in 1,2-hexanediol. In each experiment, (S,S)-(salen)Co–Cl (0.15 mol %) was added to the reaction mixture and aged for 45 min, followed by water; 3d (0.15 mol %) was added as a solution in CH2Cl2 subsequently after the indicated delay time. The black curve is derived from an experiment in which neither 3d nor CH2Cl2 was added.