Table 1. Molecular and micellar characteristics of employed ABC triblock terpolymers.
Code* | Polymer† | MCM morphology | ||
---|---|---|---|---|
SBM1 | S354B148M35280 | 4.20 | 0.70 | Spherical |
SBM2 | S306B151M34074 | 3.57 | 0.75 | Spherical |
SBM3 | S337B333M36990 | 1.78 | 0.54 | Spherical |
SBM4 | S660B674M350140 | 1.72 | 0.26 | Spherical |
SBM5 | S611B635M292127 | 1.69 | 0.23 | Spherical |
SBM6 | S277B333M43090 | 1.46 | 0.70 | Spherical |
SBM7 | S325B681M764147 | 0.84 | 0.76 | Linear |
SBM8 | S363B765M389118 | 0.84 | 0.35 | Linear |
SBM9 | S283B596M30492 | 0.84 | 0.35 | Linear |
SBM10 | S374B819M509134 | 0.80 | 0.43 | Linear |
SBM11 | S141B345M15749 | 0.72 | 0.32 | Linear |
SBM12 | S283B700M378105 | 0.71 | 0.38 | Linear |
SBV | S358B378V594120 | 1.67 | 0.81 | Spherical |
SBT1§ | S580B124T472134 | 8.23 | 0.67 | Spherical |
SBT2§ | S520B538T343132 | 1.70 | 0.32 | Spherical |
TVB1§ | T380V307B448110 | 1.77 | 0.64 | Linear |
TVB2§ | T643V293B448145 | 3.00 | 0.46 | Linear |
TVB3§ | T790V286B448165 | 3.68 | 0.40 | Linear |
TCD | T280C135D255111 | 1.17 | 0.62 | Linear |
tSfBT | tS452fB513T463392 | 0.62 | 0.45 | Linear |
NnBEO |
N178nB105EO11439 |
1.22 |
0.40 |
Linear |
*SBM=polystyrene-block-polybutadiene-block-poly(methyl methacrylate), SBV=polystyrene-block-polybutadiene-block-poly(2-vinylpyridine), SBT=polystyrene-block-polybutadiene-block-poly(tert-butyl methacrylate), TVB=poly(tert-butyl methacrylate)-block-poly(2-vinylpyridine)-block-polybutadiene, TCD=poly(tert-butyl methacrylate)-block-poly(2-(cinnamoyloxy)ethyl methacrylate)-block-poly(2-(dimethylamino)ethyl methacrylate), tSfBT=Poly(tert-butoxy styrene)-block-poly(C6F13C2H4S-ethylethylene)-block-poly(tert-butyl methacrylate)50 and NnBEO=Poly(N-isopropyl acrylamide)-block-poly(n-butyl acrylate)-block-poly(ethylene oxide)51.
†Subscripts denote number average degrees of polymerization of each block, NA, NB, NC; Superscripts give overall molecular weight in kg mol−1.
‡Volume fractions VA and VB calculated from polymer densities.
§Fraction of 1,4-butadiene units ca. 10 mol%, otherwise 90 mol%.