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Experimental and simulated linear IR spectra of acetonitrile in methanol. (a) Experimental FTIR spectra of CH3CN in MeOH at various temperatures. (b) Simulated FTIR spectra of CH3CN in MeOH at various temperatures including the hydrogen-bond exchange induced coherence transfer. (c) Simulated FTIR spectra of CH3CN in MeOH at various temperatures without the hydrogen-bond exchange; i.e., kHF = kFH = 0.
