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. Author manuscript; available in PMC: 2013 Mar 9.
Published in final edited form as: FEBS Lett. 2011 Dec 26;586(5):596–602. doi: 10.1016/j.febslet.2011.12.014

Figure 2.

Figure 2

Thermodynamic cycles for tri-tert-butylphenol in (A) ethanol/water and (B) acetonitrile. The constant CG for (A) is as described in Figure 1. In MeCN (B), the constant CG relates CH3CNH+ + Cp2Fe0 to 1/2H2 and then to H•(solv) so that the BDFE corresponds to the chemical reaction XH → X• + H•. A derivation and descriptions of the assumptions implicit in this value is given in reference [22].