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. Author manuscript; available in PMC: 2013 Mar 9.
Published in final edited form as: FEBS Lett. 2011 Dec 26;586(5):596–602. doi: 10.1016/j.febslet.2011.12.014

Figure 5.

Figure 5

Pathways for H+/e− oxidation of tBu3PhOH. ΔG° is the standard free energy change estimated using data from Figure 2 (MeCN). ΔG‡ is the barrier calculated from the Eyring equation (k = (kBT/h)exp(−ΔG‡/RT)) for the self-exchange rate constant for H• exchange.