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. Author manuscript; available in PMC: 2013 Mar 12.
Published in final edited form as: Biomacromolecules. 2012 Feb 3;13(3):683–690. doi: 10.1021/bm201555c

Table 3.

Molecular weight of various silk fibroin and ramified Si-peptide fragments obtained from trypsin proteolysis of Si-peptide-silk chimera with peptide ions sequenced by MS/MS.


Ramified fragment

Silk fibroin fragment Si-peptide fragment Theoretical MW (g.mol−1) Experimental MW (g.mol−1)
Light chain YIAQAASQVHV K 1444.795 1444.737
AWDYVDDTDKSIAILNVQEILK K 2807.458 2807.276
RLYNSR RK 1092.27 1091.466

Heavy chain GYGQGAGSAASSVSSASSR KSLSRHDHIHHH 3324.529 3323.638
DASGAVIEEQITTK R 1617.67 1618.7
EGYEYAWSSK R 1375.46 1375.674