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. Author manuscript; available in PMC: 2012 Apr 27.
Published in final edited form as: Nature. 2011 Oct 26;478(7370):502–505. doi: 10.1038/nature10535

Figure 1. X-ray crystal structure of 1.

Figure 1

Structure of [Fe(TMC)(OO)]+ (1), with thermal ellipsoids drawn at the 30% probability level, produced using ORTEP software. Hydrogen atoms are omitted for clarity. Selected bond lengths (Å): Fe–O1 1.906(4), Fe–O2 1.914(4), Fe–N1 2.192(4), Fe–N2 2.256(5), Fe–N3 2.180(5), Fe–N4 2.273(4), O1–O2 1.463(6). Selected angles (°): O1–Fe–O2 45.03(17), Fe–O1–O2 67.8(2), Fe–O2–O1 67.2(2).