Table 4.
| |||
---|---|---|---|
entry | product | time | yield (%) |
1 | 2a | 24 h | 66 |
2 | 2b | 16 h | 62 |
3 | 2c | 3 h | 45 |
4 | 2d | 5 d | 45 |
5 | 2e | 3 d | 40 |
6 | 2f | 4 d | 42 |
7 | 2g | 20 h | 29 |
Benzyl chloride (2.0 mmol), potassium alkoxymethyltrifluoroborate (3.5 mmol), PEPPSI (0.1 mmol), K2CO3 (4.0 mmol), toluene/H2O 19:1 (0.1 M), 120 °C.